Zirconia and alumina based catalysts for steam reforming of naphthalene

Francesco Ferella, Joachim Stoehr, Ida D. Michelis, Andreas Hornung

Research output: Contribution to journalArticle

Abstract

The present paper deals with experimentation of ZrO2 and Al2O3-supported catalysts for conversion of naphthalene, chosen as tar model compound of pyrolysis or gasification syngas. In particular, the reforming capacity of active metals and promoters such as Co, Ni, Fe, Cr, Ce and Pt was tested in a fixed bed reactor at temperature from 400 to 900 °C. As regards ZrO2-supported catalysts, the best results were achieved by the Ni/Fe/Pt catalyst with 96% naphthalene conversion, 78% and 280% as CO and H2 production yield at 800 °C. Regarding Al2O3-supported catalysts, they were more active on average than the zirconia ones, achieving a very good performance even at 500 °C (90–100% naphthalene conversion, 30–40% CO yield and 300–350% H2 yield at 550 °C). Influence of different amounts of alumina, montmorillonite and carbon on carrier composition as well as pellets’ size were also studied. Both zirconia and alumina catalysts showed deactivation at higher temperatures due to coke deposition, resulting in a strong H2 production drop. Regeneration of catalysts by O2 and steam as well as activation by H2 were also studied. The activated catalyst was able to convert more than 99% naphthalene at 450 °C with a CO and H2 production yield of 26% and 420%, respectively.

Original languageEnglish
Pages (from-to)614–629
Number of pages16
JournalFuel
Volume105
DOIs
Publication statusPublished - Mar 2012

Fingerprint

Aluminum Oxide
Steam reforming
Naphthalene
Zirconia
Alumina
Carbon Monoxide
Catalyst supports
Catalysts
Bentonite
Tars
Catalyst deactivation
Tar
Steam
Reforming reactions
Clay minerals
Gasification
Coke
Pyrolysis
Carbon
Metals

Keywords

  • tar
  • catalyst
  • pyrolysis
  • gasification
  • naphthalene

Cite this

Ferella, F., Stoehr, J., Michelis, I. D., & Hornung, A. (2012). Zirconia and alumina based catalysts for steam reforming of naphthalene. Fuel, 105, 614–629. https://doi.org/10.1016/j.fuel.2012.09.052
Ferella, Francesco ; Stoehr, Joachim ; Michelis, Ida D. ; Hornung, Andreas. / Zirconia and alumina based catalysts for steam reforming of naphthalene. In: Fuel. 2012 ; Vol. 105. pp. 614–629.
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Ferella, F, Stoehr, J, Michelis, ID & Hornung, A 2012, 'Zirconia and alumina based catalysts for steam reforming of naphthalene', Fuel, vol. 105, pp. 614–629. https://doi.org/10.1016/j.fuel.2012.09.052

Zirconia and alumina based catalysts for steam reforming of naphthalene. / Ferella, Francesco; Stoehr, Joachim; Michelis, Ida D.; Hornung, Andreas.

In: Fuel, Vol. 105, 03.2012, p. 614–629.

Research output: Contribution to journalArticle

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T1 - Zirconia and alumina based catalysts for steam reforming of naphthalene

AU - Ferella, Francesco

AU - Stoehr, Joachim

AU - Michelis, Ida D.

AU - Hornung, Andreas

N1 - Copyright 2012 Elsevier B.V., All rights reserved.

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AB - The present paper deals with experimentation of ZrO2 and Al2O3-supported catalysts for conversion of naphthalene, chosen as tar model compound of pyrolysis or gasification syngas. In particular, the reforming capacity of active metals and promoters such as Co, Ni, Fe, Cr, Ce and Pt was tested in a fixed bed reactor at temperature from 400 to 900 °C. As regards ZrO2-supported catalysts, the best results were achieved by the Ni/Fe/Pt catalyst with 96% naphthalene conversion, 78% and 280% as CO and H2 production yield at 800 °C. Regarding Al2O3-supported catalysts, they were more active on average than the zirconia ones, achieving a very good performance even at 500 °C (90–100% naphthalene conversion, 30–40% CO yield and 300–350% H2 yield at 550 °C). Influence of different amounts of alumina, montmorillonite and carbon on carrier composition as well as pellets’ size were also studied. Both zirconia and alumina catalysts showed deactivation at higher temperatures due to coke deposition, resulting in a strong H2 production drop. Regeneration of catalysts by O2 and steam as well as activation by H2 were also studied. The activated catalyst was able to convert more than 99% naphthalene at 450 °C with a CO and H2 production yield of 26% and 420%, respectively.

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