23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–

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Abstract

Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.

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  • 23-electron octahedral molybdenum cluster complex

    Rights statement: This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy. In: Inorganic Chemistry, 11.12.2017.], copyright © American Chemical Society after peer review and technical editing by the publisher.

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Original languageEnglish
JournalInorganic Chemistry
Early online date22 Dec 2017
DOIs
Publication statusE-pub ahead of print - 22 Dec 2017

Bibliographic note

This document is the Accepted Manuscript version of a Published Work that appeared in final form in [23-electron octahedral molybdenum cluster complex [{Mo6I8}Cl6]–. / Sutherland, Andrew J; Efremova, Olga; Shestopalov, Michael A.; Vorotnikova, Natalya A.; Vorotnikov, Yuri A.; Mironov, Yuri V.; Kitamura, Noboru; Novozhilov, Igor N.; Syrokvashin, Mikhail ; Nadolinny, Vladimir ; Kuratieva, Natalia ; Benoit, David ; Walton, Rochard; Clarkson, Guy. In: Inorganic Chemistry, 11.12.2017.], copyright © American Chemical Society after peer review and technical editing by the publisher. Funding:Russian Foundation for Basic Research (grant no. 17-03-00140) and by the Grant of the President of the Russian Federation [grant no. MK 180.2017.3], EPSRC grant EP/R006393/1

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