A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

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Abstract

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)2[Mo6I 8(NO3)6], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as "polymeric ligands" to immobilise the molybdenum cluster complex. This journal is

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Original languageEnglish
Pages (from-to)6021-6025
Number of pages5
JournalDalton Transactions
Volume43
Issue number16
Early online date17 Jan 2014
DOIs
Publication statusPublished - 28 Apr 2014

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© The Royal Society of Chemistry 2014 Funding: Marie Curie Intra-European Fellowship (project “PolyMoRe”, no. 327440) and the Russian Foundation for Basic Research (Grants nos. 12-03- 31670 and 14-04-01816). Supplementary information available online on the journal pages.

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