Thiol-containing microspheres as polymeric ligands for the immobilisation of quantum dots

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Abstract

The first demonstration "polymeric ligands" for the immobilisation of quantum dots (QDs) is presented. Specifically, thiol-containing polystyrene microspheres were synthesised and used to incorporate QDs via a swelling/doping strategy. The resultant composite materials were shown to be highly stable against QD leaching in both apolar and polar solvents and retained an identical QD emission profile to non-immobilised QDs. This straightforward approach also allows easy access to controllable and reproducible multiple-QDcontaining microspheres.

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Original languageEnglish
Pages (from-to)215-221
Number of pages7
JournalJournal of Materials Chemistry
Volume19
Issue number2
DOIs
Publication statusPublished - 1 Jan 2009

    Keywords

  • polymeric ligands, immobilisation, quantum dots, QDs, thiol-containing polystyrene microspheres, QD leaching, QD emission, non-immobilised QDs, multiple-QDcontaining, microspheres

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