The Synthesis and Properties of Some Novel Telluruin-Containing Ligands

  • Najih I. Al-Salim

    Student thesis: Doctoral Thesis › Doctor of Philosophy

    Abstract

    The preparation of sodium 2-(4-ethoxyphenyltelluro)benzoate ligand is described. It can form complexes with some of the first row transition metal ions and some post-transition ions [Co(II), Ni(II),Cu(II), Fe(III), Cr(III), T1(I), Ag(I)]. Only the thallium(1)complex shows a considerable conductivity in solution with thallium-ligand ion pairing. The other complexes are either monomeric or dimeric. Carboxylate groups are either chelating or bridging. Cu(II), Cr(III) and Fe(III) complexes show significant antiferromagnetism....
    Date of AwardApr 1987
    Original languageEnglish
    Awarding Institution
    • Aston University

    Keywords

    • synthesis
    • properties
    • novel telluruin-containing ligands

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