The preparation of sodium 2-(4-ethoxyphenyltelluro)benzoate ligand is described. It can form complexes with some of the first row transition metal ions and some post-transition ions [Co(II), Ni(II),Cu(II), Fe(III), Cr(III), T1(I), Ag(I)]. Only the thallium(1)complex shows a considerable conductivity in solution with thallium-ligand ion pairing. The other complexes are either monomeric or dimeric. Carboxylate groups are either chelating or bridging. Cu(II), Cr(III) and Fe(III) complexes show significant antiferromagnetism....
Date of Award | Apr 1987 |
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Original language | English |
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Awarding Institution | |
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- synthesis
- properties
- novel telluruin-containing ligands
The Synthesis and Properties of Some Novel Telluruin-Containing Ligands
Al-Salim, N. I. (Author). Apr 1987
Student thesis: Doctoral Thesis › Doctor of Philosophy