TY - JOUR
T1 - Approximating the large time asymptotic reaction zone solution for fractional order kinetics AnBm
AU - Trevelyan, Philip
PY - 2012/2/1
Y1 - 2012/2/1
N2 - Consider the reaction front formed when two initially separated reactants A and B are brought into contact and react at a rate proportional to A^n B^m when the concentrations A and B are positive. Further, suppose that both n and m are less than unity. Then the leading order large time asymptotic reaction rate has compact support, i.e. the reaction zone where the reaction takes place has a finite width and the reaction rate is identically zero outside of this region. In the large time asymptotic limit an analytical approximate solution to the reactant concentrations is constructed in the vicinity of the reaction zone. The approximate solution is found to be in good agreement with numerically obtained solutions. For n > m the location of the maximum reaction rate does not coincide with the centre of mass of the reaction, and further for n not equal to m this local maximum is shifted slightly closer to the zone that initially contained species A, with the reverse holding when m > n. The three limits m -> 0, n -> 1 and m, n -> 1 are given special attention.
AB - Consider the reaction front formed when two initially separated reactants A and B are brought into contact and react at a rate proportional to A^n B^m when the concentrations A and B are positive. Further, suppose that both n and m are less than unity. Then the leading order large time asymptotic reaction rate has compact support, i.e. the reaction zone where the reaction takes place has a finite width and the reaction rate is identically zero outside of this region. In the large time asymptotic limit an analytical approximate solution to the reactant concentrations is constructed in the vicinity of the reaction zone. The approximate solution is found to be in good agreement with numerically obtained solutions. For n > m the location of the maximum reaction rate does not coincide with the centre of mass of the reaction, and further for n not equal to m this local maximum is shifted slightly closer to the zone that initially contained species A, with the reverse holding when m > n. The three limits m -> 0, n -> 1 and m, n -> 1 are given special attention.
KW - Reaction-diffusion
KW - fractional order kinetics
KW - large time asymptotic
KW - approximate solutions
UR - https://www.aimsciences.org/article/doi/10.3934/dcdss.2012.5.219
UR - https://pure.southwales.ac.uk/en/publications/approximating-the-large-time-asymptotic-reaction-zone-solution-for-fractional-order-kinetics-anbm(6b7f8107-9baf-4737-83d4-59f203ee3fa6).html
U2 - 10.3934/dcdss.2012.5.219
DO - 10.3934/dcdss.2012.5.219
M3 - Article
VL - 5
SP - 219
EP - 234
JO - Discrete and Continuous Dynamics Systems Series S
JF - Discrete and Continuous Dynamics Systems Series S
IS - 1
ER -