Caesium bis­(5-bromo­salicyl­aldehyde thio­semicarbazonato-κ3O,N,S)ferrate(III): supramolecular arrangement of low-spin FeIII complex anions mediated by Cs+ cations

Robyn Elizabeth Powell; Carl H. Schwalbe; Graham J. Tizzard; Petra J. van Koningsbruggen

doi:10.1107/S2053229615001928

Caesium bis(5-bromosalicylaldehyde thiosemicarbazonato-κ³O,N,S)ferrate(III): supramolecular arrangement of low-spin Fe^III complex anions mediated by Cs⁺ cations

Robyn Elizabeth Powell, Carl H. Schwalbe, Graham J. Tizzard, Petra J. van Koningsbruggen

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and crystal structure determination (at 293 K) of the title complex, Cs[Fe(C₈H₆BrN₃OS)₂], are reported. The compound is composed of two dianionic O,N,S-tridentate 5-bromosalicylaldehyde thiosemicarbazonate(2-) ligands coordinated to an Fe^III cation, displaying a distorted octahedral geometry. The ligands are orientated in two perpendicular planes, with the O- and S-donor atoms in cis positions and the N-donor atoms in trans positions. The complex displays intermolecular N-H...O and N-H...Br hydrogen bonds, creating R₄⁴(18) rings, which link the Fe^III units in the a and b directions. The Fe^III cation is in the low-spin state at 293 K.

Original language	English
Pages (from-to)	169-174
Number of pages	6
Journal	Acta Crystallographica Section C: Structural Chemistry
Volume	71
Issue number	3
Early online date	6 Feb 2015
DOIs	https://doi.org/10.1107/S2053229615001928
Publication status	Published - Mar 2015

Bibliographical note

Acta Crystallographica Section C.
DOI: http://dx.doi.org/10.1107/S2053229615001928

Funding: EPSRC

Supplementary data avaialbe on the journal website.

Keywords

spin-crossover behaviour
low-spin state Fe(III)
crystal structure
caesium salt
salicylaldehyde thiosemicarbazone
Fe(III) coordination compound

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10.1107/S2053229615001928

Caesium bis(5-bromosalicylaldehyde
Acta Crystallographica Section C. DOI: http://dx.doi.org/10.1107/S2053229615001928
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http://scripts.iucr.org/cgi-bin/paper?S2053229615001928

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@article{5839d9bc39464f50a218b4f53dded656,

title = "Caesium bis(5-bromosalicylaldehyde thiosemicarbazonato-κ3O,N,S)ferrate(III): supramolecular arrangement of low-spin FeIII complex anions mediated by Cs+ cations",

abstract = "The synthesis and crystal structure determination (at 293 K) of the title complex, Cs[Fe(C8H6BrN3OS)2], are reported. The compound is composed of two dianionic O,N,S-tridentate 5-bromosalicylaldehyde thiosemicarbazonate(2-) ligands coordinated to an FeIII cation, displaying a distorted octahedral geometry. The ligands are orientated in two perpendicular planes, with the O- and S-donor atoms in cis positions and the N-donor atoms in trans positions. The complex displays intermolecular N-H...O and N-H...Br hydrogen bonds, creating R44(18) rings, which link the FeIII units in the a and b directions. The FeIII cation is in the low-spin state at 293 K.",

keywords = "spin-crossover behaviour, low-spin state Fe(III), crystal structure, caesium salt, salicylaldehyde thiosemicarbazone, Fe(III) coordination compound",

author = "Powell, {Robyn Elizabeth} and Schwalbe, {Carl H.} and Tizzard, {Graham J.} and {van Koningsbruggen}, {Petra J.}",

note = "Acta Crystallographica Section C. DOI: http://dx.doi.org/10.1107/S2053229615001928 Funding: EPSRC Supplementary data avaialbe on the journal website.",

year = "2015",

month = mar,

doi = "10.1107/S2053229615001928",

language = "English",

volume = "71",

pages = "169--174",

journal = "Acta Crystallographica Section C: Structural Chemistry",

issn = "2053-2296",

publisher = "Wiley",

number = "3",

}

Caesium bis(5-bromosalicylaldehyde thiosemicarbazonato-κ³O,N,S)ferrate(III): supramolecular arrangement of low-spin Fe^III complex anions mediated by Cs⁺ cations. / Powell, Robyn Elizabeth; Schwalbe, Carl H.; Tizzard, Graham J. et al.
In: Acta Crystallographica Section C: Structural Chemistry, Vol. 71, No. 3, 03.2015, p. 169-174.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Caesium bis(5-bromosalicylaldehyde thiosemicarbazonato-κ3O,N,S)ferrate(III): supramolecular arrangement of low-spin FeIII complex anions mediated by Cs+ cations

AU - Powell, Robyn Elizabeth

AU - Schwalbe, Carl H.

AU - Tizzard, Graham J.

AU - van Koningsbruggen, Petra J.

N1 - Acta Crystallographica Section C. DOI: http://dx.doi.org/10.1107/S2053229615001928 Funding: EPSRC Supplementary data avaialbe on the journal website.

PY - 2015/3

Y1 - 2015/3

N2 - The synthesis and crystal structure determination (at 293 K) of the title complex, Cs[Fe(C8H6BrN3OS)2], are reported. The compound is composed of two dianionic O,N,S-tridentate 5-bromosalicylaldehyde thiosemicarbazonate(2-) ligands coordinated to an FeIII cation, displaying a distorted octahedral geometry. The ligands are orientated in two perpendicular planes, with the O- and S-donor atoms in cis positions and the N-donor atoms in trans positions. The complex displays intermolecular N-H...O and N-H...Br hydrogen bonds, creating R44(18) rings, which link the FeIII units in the a and b directions. The FeIII cation is in the low-spin state at 293 K.

AB - The synthesis and crystal structure determination (at 293 K) of the title complex, Cs[Fe(C8H6BrN3OS)2], are reported. The compound is composed of two dianionic O,N,S-tridentate 5-bromosalicylaldehyde thiosemicarbazonate(2-) ligands coordinated to an FeIII cation, displaying a distorted octahedral geometry. The ligands are orientated in two perpendicular planes, with the O- and S-donor atoms in cis positions and the N-donor atoms in trans positions. The complex displays intermolecular N-H...O and N-H...Br hydrogen bonds, creating R44(18) rings, which link the FeIII units in the a and b directions. The FeIII cation is in the low-spin state at 293 K.

KW - spin-crossover behaviour

KW - low-spin state Fe(III)

KW - crystal structure

KW - caesium salt

KW - salicylaldehyde thiosemicarbazone

KW - Fe(III) coordination compound

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U2 - 10.1107/S2053229615001928

DO - 10.1107/S2053229615001928

M3 - Article

SN - 2053-2296

VL - 71

SP - 169

EP - 174

JO - Acta Crystallographica Section C: Structural Chemistry

JF - Acta Crystallographica Section C: Structural Chemistry

IS - 3

ER -

Caesium bis(5-bromosalicylaldehyde thiosemicarbazonato-κ³O,N,S)ferrate(III): supramolecular arrangement of low-spin Fe^III complex anions mediated by Cs⁺ cations

Abstract

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Keywords

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Caesium bis­(5-bromo­salicyl­aldehyde thio­semicarbazonato-κ3O,N,S)ferrate(III): supramolecular arrangement of low-spin FeIII complex anions mediated by Cs+ cations

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this

Caesium bis(5-bromosalicylaldehyde thiosemicarbazonato-κ³O,N,S)ferrate(III): supramolecular arrangement of low-spin Fe^III complex anions mediated by Cs⁺ cations