Criticality of the [C4mim] [BF4] + Water system

C. A. Cerdeiriña, J. Troncoso, C. Paz Ramos, L. Romani, V. Najdanovic-Visak, H. J.R. Guedes, J. M.S.S. Esperança, Z. P. Visak, M. Nunes Da Ponte, L. P.N. Rebelo

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

A study of the behavior of the response functions of the [C4mim] [BF4] + water ionic binary solution near its liquid-liquid critical point at atmospheric pressure is presented. Phase equililibrium temperatures, which allow to obtain the critical coordinates of this system, are determined. Measurements of the isobaric heat capacity per unit volume in the critical region indicate Ising-like behavior. The slope of the critical line, (dT/dp)c, is estimated by means of Prigogine and Defay's equation using experimentally determined excess volumes and excess enthalpies as a function of temperature. (dT/dp)c is found to be near zero. The consequences of this fact for the global critical behavior of second-order volumetric derivatives are discussed.

Original languageEnglish
Title of host publicationIonic Liquids IIIA
Subtitle of host publication Fundamentals, Progress, Challenges and Opportunities - Properties and Structure
EditorsRobin Rogers, Kenneth Seddon
PublisherAmerican Chemical Society
Pages175-186
Number of pages12
ISBN (Print)9780841238930, 0-8412-3893-6
Publication statusPublished - 1 Dec 2005
EventSymposium on Ionic Liquids - Fundamentals, Progress, Challenges and Opportunities - New York, United States
Duration: 7 Sep 200311 Sep 2003

Publication series

NameACS Symposium Series
Volume901
ISSN (Print)0097-6156

Symposium

SymposiumSymposium on Ionic Liquids - Fundamentals, Progress, Challenges and Opportunities
CountryUnited States
CityNew York
Period7/09/0311/09/03

Fingerprint

Water
Liquids
Atmospheric pressure
Specific heat
Enthalpy
Derivatives
Temperature

Cite this

Cerdeiriña, C. A., Troncoso, J., Ramos, C. P., Romani, L., Najdanovic-Visak, V., Guedes, H. J. R., ... Rebelo, L. P. N. (2005). Criticality of the [C4mim] [BF4] + Water system. In R. Rogers, & K. Seddon (Eds.), Ionic Liquids IIIA: Fundamentals, Progress, Challenges and Opportunities - Properties and Structure (pp. 175-186). (ACS Symposium Series; Vol. 901). American Chemical Society.
Cerdeiriña, C. A. ; Troncoso, J. ; Ramos, C. Paz ; Romani, L. ; Najdanovic-Visak, V. ; Guedes, H. J.R. ; Esperança, J. M.S.S. ; Visak, Z. P. ; Nunes Da Ponte, M. ; Rebelo, L. P.N. / Criticality of the [C4mim] [BF4] + Water system. Ionic Liquids IIIA: Fundamentals, Progress, Challenges and Opportunities - Properties and Structure. editor / Robin Rogers ; Kenneth Seddon. American Chemical Society, 2005. pp. 175-186 (ACS Symposium Series).
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abstract = "A study of the behavior of the response functions of the [C4mim] [BF4] + water ionic binary solution near its liquid-liquid critical point at atmospheric pressure is presented. Phase equililibrium temperatures, which allow to obtain the critical coordinates of this system, are determined. Measurements of the isobaric heat capacity per unit volume in the critical region indicate Ising-like behavior. The slope of the critical line, (dT/dp)c, is estimated by means of Prigogine and Defay's equation using experimentally determined excess volumes and excess enthalpies as a function of temperature. (dT/dp)c is found to be near zero. The consequences of this fact for the global critical behavior of second-order volumetric derivatives are discussed.",
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Cerdeiriña, CA, Troncoso, J, Ramos, CP, Romani, L, Najdanovic-Visak, V, Guedes, HJR, Esperança, JMSS, Visak, ZP, Nunes Da Ponte, M & Rebelo, LPN 2005, Criticality of the [C4mim] [BF4] + Water system. in R Rogers & K Seddon (eds), Ionic Liquids IIIA: Fundamentals, Progress, Challenges and Opportunities - Properties and Structure. ACS Symposium Series, vol. 901, American Chemical Society, pp. 175-186, Symposium on Ionic Liquids - Fundamentals, Progress, Challenges and Opportunities, New York, United States, 7/09/03.

Criticality of the [C4mim] [BF4] + Water system. / Cerdeiriña, C. A.; Troncoso, J.; Ramos, C. Paz; Romani, L.; Najdanovic-Visak, V.; Guedes, H. J.R.; Esperança, J. M.S.S.; Visak, Z. P.; Nunes Da Ponte, M.; Rebelo, L. P.N.

Ionic Liquids IIIA: Fundamentals, Progress, Challenges and Opportunities - Properties and Structure. ed. / Robin Rogers; Kenneth Seddon. American Chemical Society, 2005. p. 175-186 (ACS Symposium Series; Vol. 901).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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T1 - Criticality of the [C4mim] [BF4] + Water system

AU - Cerdeiriña, C. A.

AU - Troncoso, J.

AU - Ramos, C. Paz

AU - Romani, L.

AU - Najdanovic-Visak, V.

AU - Guedes, H. J.R.

AU - Esperança, J. M.S.S.

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AU - Nunes Da Ponte, M.

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N2 - A study of the behavior of the response functions of the [C4mim] [BF4] + water ionic binary solution near its liquid-liquid critical point at atmospheric pressure is presented. Phase equililibrium temperatures, which allow to obtain the critical coordinates of this system, are determined. Measurements of the isobaric heat capacity per unit volume in the critical region indicate Ising-like behavior. The slope of the critical line, (dT/dp)c, is estimated by means of Prigogine and Defay's equation using experimentally determined excess volumes and excess enthalpies as a function of temperature. (dT/dp)c is found to be near zero. The consequences of this fact for the global critical behavior of second-order volumetric derivatives are discussed.

AB - A study of the behavior of the response functions of the [C4mim] [BF4] + water ionic binary solution near its liquid-liquid critical point at atmospheric pressure is presented. Phase equililibrium temperatures, which allow to obtain the critical coordinates of this system, are determined. Measurements of the isobaric heat capacity per unit volume in the critical region indicate Ising-like behavior. The slope of the critical line, (dT/dp)c, is estimated by means of Prigogine and Defay's equation using experimentally determined excess volumes and excess enthalpies as a function of temperature. (dT/dp)c is found to be near zero. The consequences of this fact for the global critical behavior of second-order volumetric derivatives are discussed.

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BT - Ionic Liquids IIIA

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A2 - Seddon, Kenneth

PB - American Chemical Society

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Cerdeiriña CA, Troncoso J, Ramos CP, Romani L, Najdanovic-Visak V, Guedes HJR et al. Criticality of the [C4mim] [BF4] + Water system. In Rogers R, Seddon K, editors, Ionic Liquids IIIA: Fundamentals, Progress, Challenges and Opportunities - Properties and Structure. American Chemical Society. 2005. p. 175-186. (ACS Symposium Series).