Microporous organic polymers based on hexaphenylbiadamantane: synthesis, ultra-high stability and gas capture

Jianwei Guo; Xiangfeng Lai; Shuqin Fu; Hangbo Yue; Jiawei Wang; Paul D. Topham

doi:10.1016/j.matlet.2016.10.072

Microporous organic polymers based on hexaphenylbiadamantane: synthesis, ultra-high stability and gas capture

Jianwei Guo^*, Xiangfeng Lai, Shuqin Fu, Hangbo Yue, Jiawei Wang, Paul D. Topham

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Hexaphenylbiadamantane-based microporous organic polymers (MOPs) were successfully synthesized by Suzuki coupling under mild conditions. The obtained MOPs show high surface area (891 m² g⁻¹), ultra-high thermal (less than 40% mass loss at temperatures up to 1000 °C) and chemical (no apparent decomposition in organic solvents for more than 7 days) stability, gas (H₂, CO₂, CH₄) capture capabilities and vapor (benzene, hexane) adsorption. These combined abilities render the synthesized MOPs an attractive candidate as thermo-chemically stable adsorbents for practical use in gas storage and pollutant vapor adsorption.

Original language	English
Pages (from-to)	76–79
Number of pages	4
Journal	Materials Letters
Volume	187
Early online date	17 Oct 2016
DOIs	https://doi.org/10.1016/j.matlet.2016.10.072
Publication status	Published - 15 Jan 2017

Bibliographical note

© 2016, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/

Supplementary data available on the journal website.

Keywords

microporous material
adamantane
stability
adsorption

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10.1016/j.matlet.2016.10.072

Microporous organic polymers based on hexaphenylbiadamantane
© 2016, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Accepted author manuscript, 1.03 MBLicence: CC BY-NC-ND 3.0

Cite this

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abstract = "Hexaphenylbiadamantane-based microporous organic polymers (MOPs) were successfully synthesized by Suzuki coupling under mild conditions. The obtained MOPs show high surface area (891 m2 g−1), ultra-high thermal (less than 40% mass loss at temperatures up to 1000 °C) and chemical (no apparent decomposition in organic solvents for more than 7 days) stability, gas (H2, CO2, CH4) capture capabilities and vapor (benzene, hexane) adsorption. These combined abilities render the synthesized MOPs an attractive candidate as thermo-chemically stable adsorbents for practical use in gas storage and pollutant vapor adsorption.",

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AU - Guo, Jianwei

AU - Lai, Xiangfeng

AU - Fu, Shuqin

AU - Yue, Hangbo

AU - Wang, Jiawei

AU - Topham, Paul D.

N1 - © 2016, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ Supplementary data available on the journal website.

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AB - Hexaphenylbiadamantane-based microporous organic polymers (MOPs) were successfully synthesized by Suzuki coupling under mild conditions. The obtained MOPs show high surface area (891 m2 g−1), ultra-high thermal (less than 40% mass loss at temperatures up to 1000 °C) and chemical (no apparent decomposition in organic solvents for more than 7 days) stability, gas (H2, CO2, CH4) capture capabilities and vapor (benzene, hexane) adsorption. These combined abilities render the synthesized MOPs an attractive candidate as thermo-chemically stable adsorbents for practical use in gas storage and pollutant vapor adsorption.

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KW - adsorption

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JF - Materials Letters

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Microporous organic polymers based on hexaphenylbiadamantane: synthesis, ultra-high stability and gas capture

Abstract

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Keywords

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