Microporous organic polymers based on hexaphenylbiadamantane: synthesis, ultra-high stability and gas capture

Jianwei Guo, Xiangfeng Lai, Shuqin Fu, Hangbo Yue, Jiawei Wang, Paul D. Topham

Research output: Contribution to journalArticle

Abstract

Hexaphenylbiadamantane-based microporous organic polymers (MOPs) were successfully synthesized by Suzuki coupling under mild conditions. The obtained MOPs show high surface area (891 m2 g−1), ultra-high thermal (less than 40% mass loss at temperatures up to 1000 °C) and chemical (no apparent decomposition in organic solvents for more than 7 days) stability, gas (H2, CO2, CH4) capture capabilities and vapor (benzene, hexane) adsorption. These combined abilities render the synthesized MOPs an attractive candidate as thermo-chemically stable adsorbents for practical use in gas storage and pollutant vapor adsorption.
LanguageEnglish
Pages76–79
Number of pages4
JournalMaterials Letters
Volume187
Early online date17 Oct 2016
DOIs
Publication statusPublished - 15 Jan 2017

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Organic polymers
Gases
vapors
high polymers
adsorption
polymers
synthesis
adsorbents
Vapors
gases
contaminants
Adsorption
benzene
Hexanes
Benzene
Hexane
decomposition
Organic solvents
Adsorbents
Decomposition

Bibliographical note

© 2016, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/

Supplementary data available on the journal website.

Keywords

  • microporous material
  • adamantane
  • stability
  • adsorption

Cite this

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abstract = "Hexaphenylbiadamantane-based microporous organic polymers (MOPs) were successfully synthesized by Suzuki coupling under mild conditions. The obtained MOPs show high surface area (891 m2 g−1), ultra-high thermal (less than 40{\%} mass loss at temperatures up to 1000 °C) and chemical (no apparent decomposition in organic solvents for more than 7 days) stability, gas (H2, CO2, CH4) capture capabilities and vapor (benzene, hexane) adsorption. These combined abilities render the synthesized MOPs an attractive candidate as thermo-chemically stable adsorbents for practical use in gas storage and pollutant vapor adsorption.",
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Microporous organic polymers based on hexaphenylbiadamantane : synthesis, ultra-high stability and gas capture. / Guo, Jianwei; Lai, Xiangfeng; Fu, Shuqin; Yue, Hangbo; Wang, Jiawei; Topham, Paul D.

In: Materials Letters, Vol. 187, 15.01.2017, p. 76–79.

Research output: Contribution to journalArticle

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AU - Guo, Jianwei

AU - Lai, Xiangfeng

AU - Fu, Shuqin

AU - Yue, Hangbo

AU - Wang, Jiawei

AU - Topham, Paul D.

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