Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 2357-2360 |
| Number of pages | 4 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | C46 |
| DOIs | |
| Publication status | Published - 1990 |
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Bibliographical note
Faulmann, C., van Koningsbruggen, P. J., de Graaff, R. A. G., Haasnoot, J. G. & Reedijk, J. (1990). Acta Cryst. C46, 2357-2360.Keywords
- complexes
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Structure of trans-bis[4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole-N1,N'[diaqua- manganese(II) dibromide. / Faulmann, C. ; Van Koningsbruggen, Petra; de Graaff, R. A. G. ; Haasnoot , J. G. ; Reedijk, J.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. C46, 1990, p. 2357-2360.Research output: Contribution to journal › Article
TY - JOUR
T1 - Structure of trans-bis[4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole-N1,N'[diaqua- manganese(II) dibromide
AU - Faulmann, C.
AU - Van Koningsbruggen, Petra
AU - de Graaff, R. A. G.
AU - Haasnoot , J. G.
AU - Reedijk, J.
N1 - Faulmann, C., van Koningsbruggen, P. J., de Graaff, R. A. G., Haasnoot, J. G. & Reedijk, J. (1990). Acta Cryst. C46, 2357-2360.
PY - 1990
Y1 - 1990
N2 - [Mn(C12H10N6)2(H2O)2]Br2, Mr = 727.28, orthorhombic, Pbca, a = 10.734 (6), b = 17.084 (0), c = 15.182 (6) angstrom, V = 2784 angstrom 3, Z = 4, D(x) = 1.734 g cm-3, lambda-(Mo K-alpha) = 0.71073 angstrom, mu = 33.23 cm-1, F(000) = 1450, T = 295 K, final R = 0.032 for 1493 reflections [I > 2-sigma(I)]. The title compound is the first reported mononuclear compound with the ligand 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole. The manganese ions, situated on an inversion centre, are coordinated by four nitrogen atoms with an N-Mn-N angle of 74.1 (1)-degrees and Mn-N distances of 2.188 (4) and 2.266 (4) angstrom. Two axial water molecules [Mn-O = 2.200 (4) angstrom] complete the coordination sphere of the metal, which is pseudo-octahedral. The two bromide ions are not coordinated but are involved in an extended hydrogen-bridging network with the water ligands and the amino group of the triazole.
AB - [Mn(C12H10N6)2(H2O)2]Br2, Mr = 727.28, orthorhombic, Pbca, a = 10.734 (6), b = 17.084 (0), c = 15.182 (6) angstrom, V = 2784 angstrom 3, Z = 4, D(x) = 1.734 g cm-3, lambda-(Mo K-alpha) = 0.71073 angstrom, mu = 33.23 cm-1, F(000) = 1450, T = 295 K, final R = 0.032 for 1493 reflections [I > 2-sigma(I)]. The title compound is the first reported mononuclear compound with the ligand 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole. The manganese ions, situated on an inversion centre, are coordinated by four nitrogen atoms with an N-Mn-N angle of 74.1 (1)-degrees and Mn-N distances of 2.188 (4) and 2.266 (4) angstrom. Two axial water molecules [Mn-O = 2.200 (4) angstrom] complete the coordination sphere of the metal, which is pseudo-octahedral. The two bromide ions are not coordinated but are involved in an extended hydrogen-bridging network with the water ligands and the amino group of the triazole.
KW - complexes
UR - http://scripts.iucr.org/cgi-bin/paper?S0108270190005066
U2 - 10.1107/S0108270190005066
DO - 10.1107/S0108270190005066
M3 - Article
VL - C46
SP - 2357
EP - 2360
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
ER -