Temporary mirror symmetry breaking and chiral excursions in open and closed systems

Celia Blanco, Michael Stich, David Hochberg*

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

The reversible Frank model is capable of amplifying the initial small statistical deviations from the idealized racemic composition. This temporary amplification can be interpreted as a chiral excursion in a dynamic phase space. It is well known that if the system is open to matter and energy exchange, a permanently chiral state can be reached asymptotically, while the final state is necessarily racemic if the system is closed. In this work, we combine phase space analysis, stability analysis and numerical simulations to study the initial chiral excursions and determine how they depend on whether the system is open, semi-open or closed.

Original languageEnglish
Pages (from-to)140-147
Number of pages8
JournalChemical Physics Letters
Volume505
Issue number4-6
Early online date16 Feb 2011
DOIs
Publication statusPublished - 30 Mar 2011

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Open systems
broken symmetry
Mirrors
mirrors
Amplification
energy transfer
deviation
Computer simulation
Chemical analysis
simulation

Bibliographical note

© 2011, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/

Cite this

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Temporary mirror symmetry breaking and chiral excursions in open and closed systems. / Blanco, Celia; Stich, Michael; Hochberg, David.

In: Chemical Physics Letters, Vol. 505, No. 4-6, 30.03.2011, p. 140-147.

Research output: Contribution to journalArticle

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