Tunable KIT-6 mesoporous sulfonic acid catalysts for fatty acid esterification

Cyril Pirez, Jean-Michel Caderon, Jean-Philippe Dacquin, Adam F. Lee, Karen Wilson

Research output: Contribution to journalArticle

Abstract

We report the first catalytic application of pore-expanded KIT-6 propylsulfonic acid (PrSO H) silicas, in fatty acid esterification with methanol under mild conditions. As-synthesized PrSO H-KIT-6 exhibits a 40 and 70% enhancement in turnover frequency (TOF) toward propanoic and hexanoic acid esterification, respectively, over a PrSO H-SBA-15 analogue of similar 5 nm pore diameter, reflecting the improved mesopore interconnectivity of KIT-6 over SBA-15. However, pore accessibility becomes rate-limiting in the esterification of longer chain lauric and palmitic acids over both solid acid catalysts. This problem can be overcome via hydrothermal aging protocols which permit expansion of the KIT-6 mesopore to 7 nm, thereby doubling the TOF for lauric and palmitic acid esterification over that achievable with PrSO H-SBA-15.
Original languageEnglish
Pages (from-to)1607-1614
Number of pages8
JournalACS Catalysis
Volume2
Issue number8
Early online date21 Jun 2012
DOIs
Publication statusPublished - 3 Aug 2012

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Sulfonic Acids
Esterification
Fatty acids
Fatty Acids
Palmitic acid
Catalysts
lauric acid
Acids
Lauric Acids
Silicon Dioxide
Methanol
Aging of materials
Silica
SBA-15

Cite this

Pirez, C., Caderon, J-M., Dacquin, J-P., Lee, A. F., & Wilson, K. (2012). Tunable KIT-6 mesoporous sulfonic acid catalysts for fatty acid esterification. ACS Catalysis, 2(8), 1607-1614. https://doi.org/10.1021/cs300161a
Pirez, Cyril ; Caderon, Jean-Michel ; Dacquin, Jean-Philippe ; Lee, Adam F. ; Wilson, Karen. / Tunable KIT-6 mesoporous sulfonic acid catalysts for fatty acid esterification. In: ACS Catalysis. 2012 ; Vol. 2, No. 8. pp. 1607-1614.
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Pirez, C, Caderon, J-M, Dacquin, J-P, Lee, AF & Wilson, K 2012, 'Tunable KIT-6 mesoporous sulfonic acid catalysts for fatty acid esterification', ACS Catalysis, vol. 2, no. 8, pp. 1607-1614. https://doi.org/10.1021/cs300161a

Tunable KIT-6 mesoporous sulfonic acid catalysts for fatty acid esterification. / Pirez, Cyril; Caderon, Jean-Michel; Dacquin, Jean-Philippe; Lee, Adam F.; Wilson, Karen.

In: ACS Catalysis, Vol. 2, No. 8, 03.08.2012, p. 1607-1614.

Research output: Contribution to journalArticle

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Pirez C, Caderon J-M, Dacquin J-P, Lee AF, Wilson K. Tunable KIT-6 mesoporous sulfonic acid catalysts for fatty acid esterification. ACS Catalysis. 2012 Aug 3;2(8):1607-1614. https://doi.org/10.1021/cs300161a