Microporous organic polymers based on hexaphenylbiadamantane: synthesis, ultra-high stability and gas capture

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Abstract

Hexaphenylbiadamantane-based microporous organic polymers (MOPs) were successfully synthesized by Suzuki coupling under mild conditions. The obtained MOPs show high surface area (891 m2 g−1), ultra-high thermal (less than 40% mass loss at temperatures up to 1000 °C) and chemical (no apparent decomposition in organic solvents for more than 7 days) stability, gas (H2, CO2, CH4) capture capabilities and vapor (benzene, hexane) adsorption. These combined abilities render the synthesized MOPs an attractive candidate as thermo-chemically stable adsorbents for practical use in gas storage and pollutant vapor adsorption.

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Original languageEnglish
Pages (from-to)76–79
Number of pages4
JournalMaterials Letters
Volume187
Early online date17 Oct 2016
DOIs
Publication statusPublished - 15 Jan 2017

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© 2016, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ Supplementary data available on the journal website.

    Keywords

  • microporous material, adamantane, stability, adsorption

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